EXPERIMENTAL INVESTIGATION OF THE INFLUENCE OF MULTI-RECYCLING ON THE FRACTURE BEHAVIOR OF POST CONSUMER HIGH IMPACT POLYSTYRENE FROM DISPOSABLE CUPS EVALUATED BY THE J-INTEGRAL APPROACH.

Authors

  • Hanan El Bhilat National higher school of electricity and mechanics https://orcid.org/0000-0002-6328-9003
  • Hassan Mabchour Institute of Maritims Studies https://orcid.org/0000-0002-0101-3124
  • Houda Salmi National higher school of electricity and mechanics
  • Abdelilah Hachim Institute of Maritims Studies
  • Khalid El Had Institute of Maritims Studies

DOI:

https://doi.org/10.31436/iiumej.v23i1.1693

Keywords:

Recycling, High impact polystyrene, Fracture, J-integral, Extrusion

Abstract

The aim of the present paper is to study the effect of multi-recycling on the fracture behavior of high impact polystyrene from disposable cups. After collecting and washing the material, it was subjected to six cycles of recycling. After each cycle, it was subjected to tensile tests to determine the R-curves. The theory of the J-integral contour has been used for the development of a characterization method of the fracture strength appropriate to the case of this non-linear elastoplastic polymer material. To this end, the method of multiple specimens (Single edge notch tension SENT) of thin thickness was used, by introducing cracks of the same lengths to several identical test pieces. The results suggested a slight decrease in crack resistance of recycled high impact polystyrene, especially during the first cycle, demonstrated by a comparison of JIC values related to initiation of crack propagation. The fracture energy absorbed as a function of the cycles suggested a weakening within the material.

ABSTRAK: Tujuan kajian ini adalah bagi mengkaji kesan tindak balas pada pelbagai peringkat-kitar semula ke atas kerapuhan polisterin berimpak tinggi pada cawan pakai buang. Selepas mengumpul dan membasuh cawan ini, terdapat enam peringkat kitar semula. Pada setiap peringkat, ianya akan melalui ujian tegangan bagi mendapatkan lengkung-R. Teori kamiran-J kontur telah digunakan bagi mencipta kaedah khas bagi mengkaji kekuatan retakan bersesuaian bagi kes bahan polimer elastoplastik yang tidak-linear. Sehingga kini, kaedah Regangan Tepi Takuk Tunggal (SENT) telah digunakan pada spesimen berketebalan rendah, dengan menghasilkan keretakan sama panjang di permulaan kajian di buat pada pelbagai bahan uji yang serupa. Dapatan kajian menunjukkan rintangan pada retakan telah berkurang sedikit pada polisterin kitar semula berimpak tinggi, terutama pada kitaran pertama, yang ditunjukkan pada nilai JIC pada permukaan rambatan retakan awal. Tenaga kerapuhan yang meresap pada setiap kitaran menunjukkan bahan telah melemah dari dalam.

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References

Azwa ZN,Yousif BF,Manalo AC, Karunasena W. (2013), A review on the degradability of polymeric composites based on natural fibres, Materials & Design, 47(1): 424-442. https://doi.org/10.1016/j.matdes.2012.11.025 DOI: https://doi.org/10.1016/j.matdes.2012.11.025

Celina M, Linde E, Brunson D, Quintana A, Giron N. (2019) Overview of accelerated aging and polymer degradation kinetics for combined radiation-thermal environments, Polymer Degradation and Stability,166 (1): 353-378.

https://doi.org/10.1016/j.polymdegradstab.2019.06.007 DOI: https://doi.org/10.1016/j.polymdegradstab.2019.06.007

Saikrishnan S, Jubinville D, Tzoganakis C, Mekonnen TM. (2020) Thermo-mechanical degradation of polypropylene (PP) and low-density polyethylene (LDPE) blends exposed to simulated recycling. Polymer Degradation and Stability, 182(1).

https://doi.org/10.1016/j.polymdegradstab.2020.109390 DOI: https://doi.org/10.1016/j.polymdegradstab.2020.109390

Ito M, Nagai K. (2008) Degradation issues of polymer materials used in railway field, Polymer Degradation and Stability, 93(10): 1723-1735.

https://doi.org/10.1016/j.polymdegradstab.2008.07.011 DOI: https://doi.org/10.1016/j.polymdegradstab.2008.07.011

Verdu J. (2011) Vieillissement chimique des plastiques : aspects généraux, Techniques de l’Ingénieur. https://www.techniques-ingenieur.fr/base-documentaire/archives-th12/archives-plastiques-et-composites-tiaam/archive-1/vieillissement-chimique-des-plastiques-aspects-generaux-am3151/

Vranjes N, Rek V. (2007) Effect of EPDM on morphology, mechanical properties, crystallization behavior and viscoelastic properties. Macromolecular Symposia, 258(1): 90-100. https://doi.org/10.1002/masy.200751210 DOI: https://doi.org/10.1002/masy.200751210

Kallel T, Massardier-Nageotte V, Jaziri M, Gérard J F, Elleuch B. (2003) Compatibilization of PE/PS and PE/PP blends. I. Effect of processing conditions and formulation. Journal of Applied Polymer Science, 90(9): 2475-2484. https://doi.org/10.1002/app.12873 DOI: https://doi.org/10.1002/app.12873

Lin Y, Marchand G R, Hiltner A, Baer E. (2011) Adhesion of olefin block copolymers to polypropylene and high density polyethylene and their effectiveness as compatibilisers in blends. Polymer, 52(7) :1635-1644. https://doi.org/10.1016/j.polymer.2011.02.012 DOI: https://doi.org/10.1016/j.polymer.2011.02.012

Siddiqui M, Antonakou E, Redhwi H, Achilias D. (2019) Kinetic analysis of thermal and catalytic degradation of polymers found in waste electric and electronic equipment. Thermochimica Acta, 675 (1): 69-76. https://doi.org/10.1016/j.tca.2019.03.001. DOI: https://doi.org/10.1016/j.tca.2019.03.001

Sawaguchi T, Sasaki D, Takamura A. (2019) On the entanglement-based mechanism in thermal degradation of vinyl polymers, Polymer Degradation and Stability, 169(1): 108990. DOI: https://doi.org/10.1016/j.polymdegradstab.2019.108990. DOI: https://doi.org/10.1016/j.polymdegradstab.2019.108990

Hirayama D, Clodoaldo S. (2018) Morphologic and mechanical properties of blends from recycled acrylonitrile-butadiene-styrene and high-impact polystyrene, Polymer, 135 (1): 271-278. https://doi.org/10.1016/j.polymer.2017.12.038. DOI: https://doi.org/10.1016/j.polymer.2017.12.038

Lin Y, Yakovleva V, Chen H, Hiltner A, Baer E. (2009) Comparison of olefin copolymers as compatibilizers for polypropylene and high-density polyethylene. Journal of Applied Polymer Science, 113(3): 1945-1952. https://doi.org/10.1002/app.30190 DOI: https://doi.org/10.1002/app.30190

Zweifel H. (2000) Plastics Additives Handbook Munich. Hanser. (5th Edition) :900.

Mehrabzadeh M, Farahmand F. (2001) Recycling of commingled plastics waste containing polypropylene, polyethylene, and paper. Journal of Applied Polymer Science. 80(13): 2573-2577. https://doi.org/10.1002/app.1367 DOI: https://doi.org/10.1002/app.1367

Ku H, Wang N, Pattarachaiyakoop N, Trada M. (2011) A review on the tensile properties of natural fiber reinforced polymers composites. Composites, Part B,42(4): 856-873. https://doi.org/10.1016/j.compositesb.2011.01.010 DOI: https://doi.org/10.1016/j.compositesb.2011.01.010

Grein C, Gahleitner M, Bernreitner K. (2012) Mechanical and optical effects of elastomer interaction in polypropylene modification: ethylene-propylene rubber, poly-(ethyleneco-octene) and styrene-butadiene elastomers. eXPRESS Polymer Letters, 6(9): 688-696.

DOI: 10.3144/expresspolymlett.2012.74 DOI: https://doi.org/10.3144/expresspolymlett.2012.74

Ubonnut L, Thongyai S, Praserthdam P. (2007) Interfacial adhesion enhancement of polyethylene-polypropylene mixtures by adding synthesized diisocyanate compatibilizers. Journal of Applied Polymer Science,104(6): 3766-3773. https://doi.org/10.1002/app.25945 DOI: https://doi.org/10.1002/app.25945

Radonjic G, Gubeljak N. (2002) The use of ethylene/propylene copolymers as compatibilizers for recycled polyolefin blends. Macromolecular Material and Engineering, 2(287): 122-132. https://doi.org/10.1002/1439-2054(20020201)287:2<122::AID-MAME122>3.0.CO;2-A DOI: https://doi.org/10.1002/1439-2054(20020201)287:2<122::AID-MAME122>3.0.CO;2-A

Colbeaux A, Kotek J, Fenouillot F, Taha M, Wautier H, Gérard J F. (2001) Compatibilisation de mélanges polypropylène/polyéthylène par extrusion réactive. Thèse doctorat INSA Lyon, 338 p. http://theses.insa-lyon.fr/publication/2001ISAL0058/these.pdf

Almishal S, Mohamed T, Shazly M. (2020) Experimental and statistical study of the effect of temperature and waste ratio on the mechanical properties and cost of polystyrene polypropylene plastic blends, Heliyon, 6(6): e04166. https://doi.org/10.1016/j.heliyon.2020.e04166. DOI: https://doi.org/10.1016/j.heliyon.2020.e04166

Mehat NM, Kamaruddin S. (2011) Optimization of mechanical properties of recycled plastic products via optimal parameters using the Taguchi methods. Journal of Materials Processing Technology, 211(12): 1989-1994. https://doi.org/10.1016/j.jmatprotec.2011.06.014 DOI: https://doi.org/10.1016/j.jmatprotec.2011.06.014

Krulis Z, Kokta V B, Horak Z, Michalkova D, Fortelny I. (2001) Compatibilization as a procedure for recycling of commingled polyolefin waste. Macromolecular Materials and Engineering, 286(3): 156-160.

https://doi.org/10.1002/1439-2054(20010301)286:3<156::AID-MAME156>3.0.CO;2-J DOI: https://doi.org/10.1002/1439-2054(20010301)286:3<156::AID-MAME156>3.0.CO;2-J

Ritchie R, Liu D. (2021) Chapter 2 - Foundations of fracture mechanics, Introduction to Fracture Mechanics, Elsevier: 3-9. https://doi.org/10.1016/B978-0-323-89822-5.00008-6. DOI: https://doi.org/10.1016/B978-0-323-89822-5.00008-6

Irwin GR. (1957) Analysis of stresses and strains near the end of a crack traversing a plate, Journal of Applied Mechanics, 24:361-364. DOI: https://doi.org/10.1115/1.4011547

Rice JR. (1968) A path independent integral and approximate analysis of strain concentration by notches and cracks. Journal of Applied Mechanics, 35(2):379-386.

DOI: 10.1115/1.3601206 DOI: https://doi.org/10.1115/1.3601206

Begley JA, Landes JD. (1971) The effect of specimen geometry in JIc. Fracture toughness, American Society of Testing and Materials, Special Technical Publication, 514: 24-39. https://doi.org/10.1520/STP38817S DOI: https://doi.org/10.1520/STP38817S

Begley JA, Landes JD. (1971) The J-integral as a fracture criterion. Fracture toughness, American Society of Testing and Materials, Special Technical Publication, 514: 1-23. https://doi.org/10.1520/STP38816S DOI: https://doi.org/10.1520/STP38816S

Begley JA, Landes JD. (1974) Test Results from J-lntegral Studies: An Attempt to Establish a JIC Testing Procedure. Fracture Analysis, American Society for Testing and Materials, Special Technical Publication, 560:170-186. https://doi.org/10.1520/STP33140S DOI: https://doi.org/10.1520/STP33140S

Brosa V, Bernal C, Frontini P. (1999) Calibration of fracture mechanics parameters and J–R curve determination in polyethylene side-grooved arc-shaped specimens. Eng. Fract. Mech,62(2-3): 231-248. https://doi.org/10.1016/S0013-7944(98)00094-0 DOI: https://doi.org/10.1016/S0013-7944(98)00094-0

Clarke G, Landes J. (1979) Evaluation of the J Integral for the Compact Specimen. J. Test. Eval,7(5): 264-269. https://doi.org/10.1520/JTE10222J DOI: https://doi.org/10.1520/JTE10222J

Tancrez J, Pabiot J, Rietsch F. (1996) Damage and fracture mechanisms in thermoplastic-matrix composites in relation to processing and structural parameters. Compos. Sci. Technol, 56(7): 725-731. https://doi.org/10.1016/0266-3538(96)00013-9 DOI: https://doi.org/10.1016/0266-3538(96)00013-9

Huang D. (1996) The application of fracture mechanics to materials selection. Polym. Eng. Sci, 36(18): 2270-2274. https://doi.org/10.1002/pen.10625 DOI: https://doi.org/10.1002/pen.10625

Kumar S, Singh R. (2003) Primary and Secondary Recycling of Thermosetting Polymers: A Review. Reference Module in Materials Science and Materials Engineering, 73(9): 1775. https://doi.org/10.1002/mame.200390005 DOI: https://doi.org/10.1002/mame.200390005

Wrozynski RJ, Rubinsztajn M, Potyrailo RA. (2004) Evaluation of Process Degradation of Polymer Formulations Utilizing High?Throughput Preparation and Analysis Methods. Macromolecular rapid communication, 2(1): 264-269.

https://doi.org/10.1002/marc.200300167 DOI: https://doi.org/10.1002/marc.200300167

Bartolomeo P. (2003) Deriving a prediction of the life cycle of géosynthrtic polymers. Bulletins des laboratoires des Pont et Chaussées, N°243-Réf 4456, p.51.

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Published

2022-01-04

How to Cite

EL BHILAT, H., Hassan, M., Houda, S., Abdelilah, H., & Khalid, E. H. (2022). EXPERIMENTAL INVESTIGATION OF THE INFLUENCE OF MULTI-RECYCLING ON THE FRACTURE BEHAVIOR OF POST CONSUMER HIGH IMPACT POLYSTYRENE FROM DISPOSABLE CUPS EVALUATED BY THE J-INTEGRAL APPROACH . IIUM Engineering Journal, 23(1), 268–281. https://doi.org/10.31436/iiumej.v23i1.1693

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Section

Materials and Manufacturing Engineering

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